Product ID:TRIADINE 10 (PREVIOUSLY KNOCK-OUT)
MSDS Date:01/26/1990
FSC:6840
NIIN:00N043131
MSDS Number: BSYTD

OLIN

120 ONG RIDGE RD
STAMFORD, CT 06904-1355
US

Emergency Phone: 800-654-6911

Info Phone: 203-356-3449

Cage: IO565

OLIN CORPORATION

4500 NORWALK, CT 06856-4500 US

Telephone: 203-750-3000/800-511-MSDS

Cage: 99530

NAUS, HDCH/DIZZ, PERSON SHLD STOP WORK IMMED

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

DFCLT, ADMIN O*2, KEEP WARM & AT REST. CALL MD. IF

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

ONCE & CALL MD IMMED. IF BRTHG STOPPED, ARTF RESP

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

PROVIDE RESP PROT BEFORE PERSON RETURNS TO WORK.

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

BY USE OF WATER FOG. CONTAIN ALL LIQ FOR

RTECS: 9999999ZZ

MISCIBLE IN WATER. NOTIFY ALL DOWNSTREAM WATER USERS

RTECS: 9999999ZZ

POSS & SAFE TO DO SO. REMOVE W/VACUUM SYS/PUMPING

RTECS: 9999999ZZ

CREATE DIKE/TRENCH TO

RTECS: 9999999ZZ

SAND/COMMERCIAL ABSORB. DO NOT PLACE MATL BACK IN

RTECS: 9999999ZZ

PROPERLY. DECONTAM CLTHG & SPILL AREA USING

RTECS: 9999999ZZ

VACUUM SYSTEM OR NETWORK OF PUMPS.

RTECS: 9999999ZZ

CARE MUST BE TAKEN TO PVNT ENVIRON CONTAM

RTECS: 9999999ZZ

UNUSED MATL, RESIDUES & CNTNRS IN COMPLIANCE W/ALL

RTECS: 9999999ZZ

TREATMENT, STORAGE & DISPOSAL FOR HAZ & NONHAZ

RTECS: 9999999ZZ

IMMED AVAILABLE IN AREA WHERE MATERIALS

RTECS: 9999999ZZ

S-TRIAZINE-1,3,5(2H,4H,6H)-TRIETHANOL;

CAS: 4719-04-4

RTECS: XZ1600000

Fraction By Weight: 60-65%

OSHA PEL N/K

ACGIH TLV: N/K

2-PYRIDINETHIOL, N-OXIDE, SODIUM

CAS: 3811-73-2

RTECS: UT9000000

Fraction By Weight: 5-10%

OSHA PEL N/K

ACGIH TLV: N/K

WATER; (DEMINERALIZED WATER)

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 25-35%

OSHA PEL N/K

ACGIH TLV: N/K

PERIPHERAL NERVE DMG CHARACT BY GEN MUSC WEAK.

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

CHRONIC TOX VIA THIS ROUTE HIGHLY UNLIKELY.

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:LD50: (ORAL, RAT) 0.75 G/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:MILD IRRIT TO THROAT,
UPPER RESP TRACT & LUNGS. HIGH EXPOS MAY CAUSE PULM EDEMA. SYMPS
MAY INCL TREMORS, ATAXIA, CONVL & IMPAIRED LIMB FUNC. SKIN:SEV
IRRIT. MAY PRDCE BURNS UPON PRLNG CNTC T. ALLERGIC SENSIT IN SOME
PERSONS. SYMPS MAY INCL TREMORS, ATAXIA, CONVL & IMPAIRED LIMB
FUNC. EYES: (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:SIGNIFICANT IRRIT & INFLAMM TO CONJ
W/CORNEAL OPACITY & DMG. IMPAIRMENT OF VISION MAY RSLT. WASHING
IMMED FOLLOWING EXPOS RSLTS IN ONLY MILD IRRIT W/OUT CORNEAL DMG.
INGEST: GASTROENTERITIS W /NAUS, VOMIT, LETHARGY & DIARR. MATL
CAUSES VOMIT, THEREFORE WOULD BE EXPECTED SHORTLY (W/IN 5-10 MIN)
FOLLOWING (SUPDAT
Medical Cond Aggravated by Exposure:DISEASES OF MUSCLE & NERVE, EG
MUSCULAR DYSTROPHY OR MULTIPLE SCLEROSIS, MAY BE AGGRAVATED BY
EXPOSURE. DERMATITIS MAY BE AGGRAVATED FOLLOWING EXPOSURE.

First Aid:EYES:IMMED FLUSH W/LG AMTS WATER FOR @ LEAST 15 MIN, OCCAS
LIFTING UPPER & LOWER EYELIDS. CALL MD @ ONCE. SKIN:IMMED FLUSH
W/WATER FOR @ LEAST 15 MIN. CALL MD. IF CLTHG COMES IN CNTCT
W/PROD, SHOULD B E REMOVED IMMED & LAUNDERED BEFORE REUSE.
INGEST:IMMED DRINK LG QTYS WATER. INDUCE VOMIT. CALL MD @ ONCE. DO
NOT GIVE ANYTHING BY MOUTH IF PERSON UNCON/IF HAVING CONVL.
INHAL:IF PERSON EXPER (ING 6)

Flash Point Method:COC
Flash Point:NONFLAMMABLE
Extinguishing Media:NOT APPLICABLE. CHOOSE EXTINGUISHING MEDIA SUITABLE
FOR SURROUNDING MATERIALS.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
ADDNL PROT CLTHG MUST BE WORN TO PVNT PERSONAL CNTCT W/MATL.
COMPATIBLE MATLS FOR RESPONSE TO MATL (SUPDAT)
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:EVACUATE NON-ESSNTL PERS. HAZ CONC IN AIR MAY
BE FOUND IN LOCAL SPILL AREA. UTILIZE EMER RESPONSE PERSONAL PROT
EQUIP PRIOR TO START OF ANY RESPONSE. STOP SOURCE OF SPILL AS SOON
AS POSS & NOTIFY APPR OP PERS. AIR RELS:VAP MAY BE SUPPRESSED(ING
10)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE AT TEMPS > 108F(42C). DO
NOT EXPOSE TO DIRECT LIGHT.
Other Precautions:DO NOT TAKE INTERNALLY. AVOID CONTACT WITH SKIN, EYES
& CLOTHING. UPON CONTACT WITH SKIN OR EYES, WASH OFF WITH WATER.

Respiratory Protection:RESPIRATOR PROTECTION NOT NORMALLY NEEDED SINCE
VOLATILITY AND TOXICITY ARE LOW. IF VAPORS, MISTS OR AEROSOLS ARE
GENERATED, WEAR NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:LOC EXHAUST VENTILATION RECOM IF VAPORS, MISTS/AEROSOLS ARE
GENERATED. OTHERWISE, USE GENERAL EXHAUST VENTILATION.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPRVD CHEM WORK GOG/FULL FSHLD FPN
Other Protective Equipment:BOOTS, APRON. FULL IMPERMEABLE SUIT RECOM IF
EXPOS POSS TO LG PORTION OF BODY. EYE WASH & SFTY SHOWER SHLD BE
(ING 20)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
PH:10-11 @ 25C (10% SOLN IN NEUT DISTILLED WATER). FIRE FIGHT PROC:ARE
NEOPRENE, CHLORINATED POLYETHYLENE, POLYVINYL CHLORIDE, BUTYL
RUBBER, VITON, POLYVINYL ALCOHOL & SARANEX. USE WATER TO COOL CNTNR
S EXPOS TO FIRE. EFTS OF OVEREXP:EXPOS.CHRONIC:INHAL:IRRIT TO RESP
TRACT. INHAL & SKIN:SKELETAL MUSC ATROPHY & (ING 4)

HCC:T6
Boiling Pt:B.P. Text:230F,110C
Melt/Freeze Pt:M.P/F.P Text:-33F,-36C
Vapor Pres:15.3 @ 25C
Spec Gravity:1.17
pH:SUPDAT
Evaporation Rate & Reference:<1 (H2O=1)
Solubility in Water:COMPLETELY MISCIBLE
Appearance and Odor:CLEAR, AMBER LIQUID. ODOR:MILD AMINE.
Percent Volatiles by Volume:30

Stability Indicator/Materials to Avoid:YES
EXPOSURE TO STRONG ACIDS OR OXIDIZING AGENTS.
Stability Condition to Avoid:TEMPERATURES ABOVE 108F (42C). (DECOMPOSES
SLOWLY)
Hazardous Decomposition Products:CARBON MONOXIDE, SULFUR DIOXIDE,
NITROGEN OXIDES, FORMALDEHYDE.
Conditions to Avoid Polymerization:CONCENTRATED ACIDS, STRONG OXIDIZING
AGENTS.

Waste Disposal Methods:PROD DOES NOT MEET CRITERIA OF HAZ WASTE AS
DEFINED BY 40CFR 261, IN THAT DOES NOT EXHIBIT CHARACT OF HAZ WASTE
OF SUBPART C, NOR LISTED AS HAZ UNDER SUBPART D. AS NONHAZ LIQ
WASTE, IT SHLD BE DISP OF I/A/W LOCAL, STATE & FED REGS BY INCIN.
(ING 17)

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